Expt. 44 - Addition of Singlet Diflurocarbene to Ethylene
AM1 Heats of Formation (kcal/mol)
|
Difluorocarbene |
-67.957 |
|
Ethylene |
16.471 |
|
Transition State |
-34.316 |
|
1,1-difluoroyclopropane |
-77.051 |
D Hrxn = S D Hf (P) - S D Hf (R) = [-77.051 - (-67.957 + 16.471)] kcal/mol= -25.565 kcal/mol